3M AUSTRALIA PTY LIMITED 2-74 Dunheved Circuit ST MARYS NSW 2760 Phone: 136-136 Fax: (02) 9677-5170 EMERGENCY PHONE: (02) 9677-5333 (available 24 hours) ======================================================================== MATERIAL SAFETY DATA SHEET ======================================================================== Document ID : 05-7455-8 Issue date : 29/04/2003 Version : 2.07 Supersedes date : 17/04/2003 Document status : Issued This MSDS has been prepared by 3M Australia Pty Limited Toxicology Department ------------------------------------------------------------------------ 1 IDENTIFICATION ------------------------------------------------------------------------ NOTE: Hazardous according to criteria of NOHSC Australia. PRODUCT NAME 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD LOW ODOUR 3M Product ID 98-0701-4071-4 98-0701-4073-0 0344333 DIVISION DO-IT-YOURSELF/CONSTRUCTION MARKETS DIV INTENDED USE OF PRODUCT To protect concrete from the intrusion of destructive chloride ions, freeze-thaw damage, deterioration of parking ramps, vehicular bridge decks, roadways, airport runways, taxiways, aprons, hangars, docks. UN NUMBER NONE ALLOCATED PROPER SHIPPING NAME NONE ALLOCATED DANGEROUS GOODS CLASS NONE ALLOCATED SUBSIDIARY RISK NONE ALLOCATED PACKING GROUP NONE ALLOCATED POISONS SCHEDULE NONE ALLOCATED ------------------------------------------------------------------------ 2 PHYSICAL/CHEMICAL PROPERTIES ------------------------------------------------------------------------ TOP OF NEW PAGE 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD Page 2 of 8. LOW ODOUR ------------------------------------------------------------------------ Appearance and Odour Liquid Boiling point 115 C Vapour pressure 0.1 mmHg @ 25C Vapour density > 1.00 (Air=1) Evaporation rate < 1.00 (BuOAc=1) Solubility in Water Negligible (<0.1%) Specific gravity ca 1.07 (Water=1) Volatile organic compounds < 50 g/L (Based on Parts A & B combined) pH Not applicable Viscosity 20.0 centipoise Melting point Not determined Flash point > 93.3 C Flammable Limits - LEL Not determined Flammable Limits - UEL Not determined Autoignition temperature Not determined ------------------------------------------------------------------------ 3 COMPOSITION ------------------------------------------------------------------------ Ingredient Name CAS number Percentage ------------------------------------- ------------------ ------------- HIGH MOLECULAR WEIGHT METHACRYLATE 31621-69-9 85.0 - 95.0 ESTER ADDUCTS --- 1.0 - 5.0 COBALT COMPOUND --- < 0.3 PHENOTHIAZINE 92-84-2 < 0.04 TOP OF NEW PAGE 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD Page 3 of 8. LOW ODOUR ------------------------------------------------------------------------ ------------------------------------------------------------------------ 4 HEALTH HAZARDS ------------------------------------------------------------------------ Effects from Eye Contact May cause mild eye irritation. Signs/symptoms can include redness, swelling, pain and tearing. Vapours may cause eye irritation. Effects from Skin Contact Moderate skin irritation: Signs/symptoms can include redness, swelling, itching and dryness. Effects from Inhalation Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Irritation to the gastrointestinal tract. Signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, diarrhoea and vomiting. ------------------------------------------------------------------------ 5 FIRST AID ------------------------------------------------------------------------ EYE CONTACT In case of contact with eyes, rinse immediately with plenty of water. Get immediate medical attention. SKIN CONTACT Wash affected area with plenty of water. Remove immediately all contaminated clothing. If irritation persists, contact a doctor. Wash contaminated clothing before reuse. INHALATION If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, seek medical attention. SWALLOWED If swallowed, drink two glasses of water and contact a doctor or Poisons Information Centre. TOP OF NEW PAGE 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD Page 4 of 8. LOW ODOUR ------------------------------------------------------------------------ ------------------------------------------------------------------------ 6 FIRE FIGHTING MEASURES ------------------------------------------------------------------------ SUITABLE EXTINGUISHING MEDIA Water spray. Carbon dioxide. Dry chemical. FIRE FIGHTING PROCEDURES Wear full protective clothing, including helmet, self-contained, positive pressure or positive pressure demand self-contained breathing apparatus, tunic and pants, bands around arms, waist and legs, full facepiece, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers exposed to heat from fire may build pressure and explode. ------------------------------------------------------------------------ 7 ACCIDENTAL RELEASE MEASURES (SPILL) ------------------------------------------------------------------------ Personal Precautions Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Spill Response Extinguish all ignition sources. Collect as much of the spilled material as possible. Clean up residue. Place residue in a closed container. For information on the 3M range of Sorbent materials, call 3M OH&ES on Freecall 1800 024-464. Methods for Disposal Do not release to waterways or sewer. As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. Dispose of completely cured (or polymerised) material in a sanitary landfill. Special Instructions, Accidental Release Contain spill with inert material. Keep spills and runoff out of municipal sewers and open bodies of water. TOP OF NEW PAGE 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD Page 5 of 8. LOW ODOUR ------------------------------------------------------------------------ ------------------------------------------------------------------------ 8 HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool place, out of direct sunlight. Keep container dry. Incompatibility - Materials to Avoid Store away from heat. Store out of direct sunlight. Recommended Ventilation Keep container in well-ventilated area. Use Instructions Keep container tightly closed when not in use. ------------------------------------------------------------------------ 9 EXPOSURE CONTROLS/PROTECTION ------------------------------------------------------------------------ Special Information, Exposure/Protection The extent to which the following recommendations for exposure control and protection are observed should depend on the risk assessment undertaken for the specific conditions under which this product is used, including occupational hygiene measurements. Eye Protection Avoid eye contact with vapour, spray, or mist. During operations in which eye exposure is likely, the following should be worn alone, or in combination, as appropriate: Safety glasses with side shields. Eye protection should comply with AS/NZS1337. When applying large quantities during high temperatures with little or no air movement, it is recommended that a full facepiece respirator be worn to prevent eye irritation. Hand Protection During operations in which hand exposure is likely, wear elbow length gloves. Gloves made from one of the following material(s) are recommended: Butyl rubber. Neoprene. Skin Protection Avoid skin contact. Use one or more of the following personal protection items as necessary to prevent skin contact: Coveralls. or long sleeved shirt and pants. For footwear, knee length rubber boots should be worn. TOP OF NEW PAGE 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD Page 6 of 8. LOW ODOUR ------------------------------------------------------------------------ Respiratory Protection Avoid breathing vapours, mists or spray. During operations in which inhalation exposure is likely, respiratory protection should be used. Select and use respirators in accordance with AS/NZS1715. When required, use one of the following: Half-facepiece organic vapour respirator. Full-face organic vapour respirator. A full facepiece respirator (e.g. 6000 Series Full Facemasks with A1 organic filters) where large quantities are applied and ventilation is not sufficient to remove irritating vapours. For information about respirators, call 3M on 1800 024464. Prevention of Accidental Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Recommended Ventilation Use with adequate dilution ventilation. If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide local exhaust or dilution ventilation to control vapours during product use. ------------------------------------------------------------------------ 10 EXPOSURE STANDARDS ------------------------------------------------------------------------ PHENOTHIAZINE (92-84-2) NOHSC EXPOSURE STANDARDS: TWA 1ppm Overall exposure for this substance will be influenced by skin exposure, including mucous membranes and eyes, either by airborne or more particularly by direct contact with the substance. The presence of other solvents may alter skin absorption. ------------------------------------------------------------------------ 11 STABILITY AND REACTIVITY ------------------------------------------------------------------------ STABILITY AND REACTIVITY Stable. Hazardous polymerisation may occur. INCOMPATIBILITY-MATERIALS TO AVOID Strong acids. Strong bases. Strong Oxidising Agents. Reducing agents. Heat. Free radical initiators, organic peroxides TOP OF NEW PAGE 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD Page 7 of 8. LOW ODOUR ------------------------------------------------------------------------ HAZARDOUS DECOMPOSITION PRODUCTS Carbon Monoxide, Carbon Dioxide. ------------------------------------------------------------------------ 12 ECOTOXICITY ------------------------------------------------------------------------ ENVIRONMENTAL DATA Not determined Other Ecotoxicity Information Environmental information is available upon request. ------------------------------------------------------------------------ 13 DISPOSAL CONSIDERATIONS ------------------------------------------------------------------------ Special Instructions for Disposal Do not release to waterways or sewer. As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. Dispose of completely cured (or polymerised) material in a sanitary landfill. Contact your local waste authority to determine suitable disposal methods. ------------------------------------------------------------------------ 14 REGULATORY INFORMATION ------------------------------------------------------------------------ Product Certifications AICS - Yes; components checked Special Regulatory Information Xi (Irritant) R Codes: 36/37/38 S Codes: 23C-51-24/25-37-39a-26-28b ------------------------------------------------------------------------ 15 OTHER INFORMATION ------------------------------------------------------------------------ REASON FOR REISSUE 10/6/97 Transport information changed to not dangerous. Refer T.Le 21/11/01 Disposal recommendations updated. 16/4/03 Risk & Safety Codes added. PPE in Hand & Skin protection clarified. TOP OF NEW PAGE 3M BRAND CONCRETE PROTECTOR AND RESTORER 5741 HIGH MOD Page 8 of 8. LOW ODOUR ------------------------------------------------------------------------ 17/4/03 Additional statements added to Eye & Respiratory Protection and ventilation sections. 29/4/03 Temperature added to Vapour Pressure in Physical/Chemical Properties section. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet, which involves using the product, or otherwise that in accordance with instructions of use on product packaging is the responsibility of the user. If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user should contact the Snr Regulatory Services Officer on (02) 9677-5179.